Nguyễn Văn Chí * , Nguyễn Phương Tùng , Phạm Duy Khanh Trần Ngọc Quyển

* Người chịu trách nhiệm về bài viết: Nguyễn Văn Chí (email: chi.nv@vlu.edu.vn)

Abstract

Dehydration of glucose into 5-hydroxymethylfurfural (HMF) was one of the most reactions in biomass conversion into high-value chemicals. This work aims to synthesize a catalyst for the efficient production of HMF from glucose. P-UiO-66 has been prepared and characterized using X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), and Fourier-transform Infrared Spectroscopy (FT-IR). The synthesized catalyst showed excellent performance for the conversion of glucose into HMF. 99% HMF was achieved under optimal conditions (180oC, 8 h, 0.05 g catalyst). In addition, the P-UiO-66 was stable and highly active during the reaction condition, which can be reused four times without a significant decrease in HMF yield.

Keywords: 5-hydroxylmethylfurfural, heterogeneous catalyst, Glucose conversion, P-UiO-66

Tóm tắt

Phản ứng tách nước từ glucose thành 5-hydroxymethylfurfural (HMF) là một phản ứng quan trọng của quá trình chuyển hóa nguyên liệu sinh khối. Nghiên cứu này nhằm tổng hợp chất xúc tác để sản xuất HMF từ glucose với hiệu suất cao. Vật liệu P-UiO-66 đã được tổng hợp và xác định tính chất thông qua nhiễu xạ nhiễu xạ X-ray (XRD), kính hiển vi điện tử quét (SEM) và phổ hồng ngoại (FT-IR). Chất xúc tác tổng hợp thể hiện hoạt tính rất cao trong phản ứng tách nước từ glucose thành HMF. Hiệu suất HMF thu được là 99% trong điều kiện tối ưu (180oC, 8  giờ, 0,05 g chất xúc tác). Hơn nữa, chất xúc tác này có độ bền cao và có thể tái sử dụng bốn lần mà không giảm hoạt tính đáng kể.  

Từ khóa: Chuyển hóa glucose, 5-hydroxylmethylfurfural, P-UiO-66, xúc tác dị thể

Article Details

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