Synthesis of Fe3O4/lignin for methylene blue treatment application
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Abstract
This study is aimed to synthesize Fe3O4/lignin materials and evaluate the material's ability to handle methylene blue. In which, Fe3O4 was synthesized by co-precipitation method, lignin was extracted from sugarcane bagasse, and Fe3O4/lignin materials were combined through citric acid binding agent. The as-synthesized materials were evaluated by advanced analytical methods such as X-ray diffraction techniques to determine the structural characteristics of Fe3O4 particles; Fourier transform infrared spectroscopy techniques to determine the presence of molecular bonding in the adsorbent; optical microscopy to determine the surface morphology of Fe3O4/lignin. The saturation magnetization of Fe3O4 particles and Fe3O4/lignin materials determined by vibrating sample magnetometer is 95 and 49.5 emu.g-1, respectively. Fe3O4/lignin adsorption and desorption capacity of methylene blue was evaluated by UV-Vis method. As a result, the maximum adsorption efficiency of Fe3O4/lignin for methylene blue could reach 96.53% at pH 6-7 within 60 minutes and the desorption efficiency was 66.5% at 75 minutes. The treatment of methylene blue was fitted to pseudo-second order model and Langmuir isotherm adsorption model.
Tóm tắt
Nghiên cứu này được thực hiện nhằm tổng hợp vật liệu Fe3O4/lignin và đánh giá khả năng xử lý methylene blue của vật liệu. Trong đó, Fe3O4 được tổng hợp bằng phương pháp đồng kết tủa, lignin được trích ly từ bã mía và vật liệu Fe3O4/lignin được kết hợp thông qua tác nhân liên kết citric acid. Các vật liệu sau khi tổng hợp được đánh giá bởi các phương pháp phân tích hiện đại như kỹ thuật nhiễu xạ tia X để xác định đặc điểm cấu trúc của các hạt Fe3O4; kỹ thuật quang phổ hồng ngoại biến đổi Fourier để xác định sự có mặt của các liên kết trong phân tử vật liệu hấp phụ; kính hiển vi quang học để xác định hình thái bề mặt của Fe3O4/lignin. Độ bão hòa từ của các hạt Fe3O4 và Fe3O4/lignin được xác định bằng từ kế mẫu rung lần lượt là 95 và 49,5 emu.g-1. Khả năng hấp phụ và nhả hấp phụ methylene blue của Fe3O4/lignin được đánh giá bằng phương pháp UV-Vis. Kết quả cho thấy hiệu suất hấp phụ tối đa của Fe3O4/lignin đối với metylen blue có thể đạt 96,53% ở pH 6-7 trong 60 phút và hiệu suất nhả hấp phụ là 66,5% trong 75 phút. Việc xử lý metylene blue tuân theo mô hình động học giả kiến bậc hai và mô hình hấp phụ đẳng nhiệt Langmuir.
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