Đánh giá khả năng hấp phụ methylene bule trong nước của vật liệu composite tổng hợp từ phụ phẩm bã mía
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Abstract
This study aimed to synthesize bead adsorbent and evaluate its adsorption performance to methylene blue by the influence of various factors such as pH, time and concentration. The results of thermogravimetric analysis, Fourier transform infrared spectroscopy, scanning electron microscopy, specific surface area analysis and surface potential revealed that the materials were successfully synthesized, with the typical groups of chitosan and of alginate. The adsorbent bead adsorbed Methylene blue with a yield of 85.33 ± 0.85% corresponding to adsorption capacity of 4.27 mg/g at optimal conditions of pH 8, adsorption time of 3 hours and concentration of 10 ppm. The adsorption of Methylene blue followed Freundlich isotherm model, the Pseudo-second order model and was a physical adsorption process.
Tóm tắt
Nghiên cứu được thực hiện với mục tiêu là tổng hợp vật liệu hấp phụ dạng hạt và đánh giá khả năng hấp phụ Methylene blue trong nước của vật liệu với sự ảnh hưởng bởi các yếu tố: pH, thời gian, nồng độ. Kết quả của phân tích nhiệt trọng lượng, phổ hồng ngoại biến đổi Fuorier, hiển vi điện tử quét, diện tích bề mặt riêng và điện tích bề mặt cho thấy vật liệu được tổng hợp thành công, có các nhóm chức đặc trưng của chitosan và của sodium alginate. Hạt vật liệu hấp phụ Methylene blue với hiệu suất 85,33 ± 0,85% ứng với dung lượng 4,27 mg/g ở các điều kiện tối ưu pH 8, thời gian hấp phụ 3 giờ và nồng độ 10 ppm. Quá trình hấp phụ Methylene blue tuân theo mô hình hấp phụ đẳng nhiệt Freundlich, có động học hấp phụ giả định bậc 2 và là quá trình hấp phụ vật lý.
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