Metal organic frameworks based on single and interpenetrated frames

Nguyen Thi Tuyet Nhung * , Nguyen Duy Khanh , Nguyen Minh Toan and Nguyen Anh Thu

* Corresponding author (tuyetnhung@ctu.edu.vn)

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Received: 01 May 2020
Accepted: 28 Oct 2020
Published: 28 Oct 2020
Title: Metal organic frameworks based on single and interpenetrated frames
DOI: 10.22144/ctu.jvn.2020.113
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How to Cite
Nhung, N. T. T., Khánh, N. D., Toàn, N. M., & Thư, N. A. (2020). Metal organic frameworks based on single and interpenetrated frames. CTU Journal of Science, 56(5), 65-71. https://doi.org/10.22144/ctu.jvn.2020.113
Issue
Vol. 56 No. 5 (2020)
Section
Natural Sciences

Abstract

Single (MT-1) and inter-penetrated (int-MT-1) metal organic frameworks were synthesized via solvothermal method from the reaction of zinc nitrate hexahydrate and 1,4-benzenedicarboxylic acid in N,N¢-dimethylformamide (DMF). The morphologies of resulting materials were observed under NHV-CAM microscope. The structures of the single and inter-penetrated frameworks respectively resulted in MT-1 and int-MT-1 were analyzed by powder X-ray diffraction analysis (PXRD) and their thermal stability was also determined by thermal gravimetric analysis (TGA). The porosity of these two materials was proved by Brunauer-Emmett-Teller (BET) method through N2 isotherms at 77 K. The results showed that two materials with single and inter-penetrated frameworks were successfully synthesized as expected. Both materials are highly crystalline with high thermal stability and porosity.
Keywords: Crystallinity, inter-penetrated framework, metal-organic frameworks, porosity, single framework, thermal stability

Tóm tắt

Vật liệu khung cơ kim khung sườn đơn (MT-1) và khung sườn đan xen (int-MT-1) được tổng hợp bằng phương pháp nhiệt dung môi từ muối kẽm nitrate và 1,4-benzenedicarboxylic acid trong dung môi N,N¢-dimethylformamide (DMF). Hình dáng của vật liệu tạo thành được xác định bằng kính hiển vi kỹ thuật số NHV-CAM. Cấu trúc khung sườn đơn và khung sườn đan xen của vật liệu tạo thành được xác định bằng phương pháp nhiễu xạ tia X dạng bột (PXRD) và sự khác nhau về độ bền nhiệt của chúng được chứng minh bằng phương pháp phân tích nhiệt trọng lượng (TGA). Độ xốp của vật liệu được xác định bằng phương pháp Brunauer-Emmett-Teller (BET) qua đường hấp phụ đẳng nhiệt N2 ở 77 K. Kết quả cho thấy vật liệu khung cơ kim khung sườn đơn và khung sườn đan xen được tổng hợp thành công như mong đợi. Cả hai vật liệu đều có độ kết tinh tốt, độ bền nhiệt cao và diện tích bề mặt riêng lớn.
Từ khóa: Độ bền nhiệt, độ kết tinh, độ xốp, khung sườn đan xen, khung sườn đơn, vật liệu khung cơ kim

Article Details

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