Nguyen Tri Tuan * , Vu Thi Hang and Nguyen Trong Tuan

* Corresponding author (trituan@ctu.edu.vn)

Abstract

ZnO nanorods with the average size of 60 nm×450 nm were successfully fabricated by hydrothermal synthesis method in the presence of ZnCl2 and NH3 solution as the starting materials at 190-230oC for 20 hours. The powder samples was characterized by means of X-ray powder diffraction (XRD), Field Emission Scan Electron Microscopy (FESEM) and Energy-Dispersive X-ray spectroscopy (EDX). The photoluminescence (PL) properties of the sample were investigated. Some factors affecting the morphologies and optical properties were also studied.
Keywords: ZnO nanorods, Hydrothermal synthesis

Tóm tắt

Que nano có kích thước trung bình 60 nm x 450 nm, được chế tạo thành công bằng phương pháp thủy nhiệt, với chất ban đầu là ZnCl2 và NH3 và que nano ZnO được hình thành ở nhiệt độ 190-230 oC trong 20 h. Mẫu bột chế tạo được đem đi đo nhiễu xạ tia X (XRD), ảnh hiển vi điện tử quét phát xạ trường và phổ năng lượng tán xạ tia X (EDX). Tính chất huỳnh quang của mẫu đã được khảo sát. Một vài thông số ảnh hưởng đến hình thái học và tính chất quang cũng được nghiên cứu.
Từ khóa: Que nano ZnO, tổng hợp thủy nhiệt

Article Details

References

Hanmei Hu, Xianhuai Huang, Chonghai Deng, Xiangying Chen, Yitai Qian, 2007. Hydrothermal synthesis of ZnO nanowires and nanobelts on a large scale, Materials Chemistry and Physics, 106: 58 - 62.

Huiying Wei, Youshi Wu, Ning Lun, Chunxia Hu, 2005. Hydrothermal synthesis and characterization of ZnO nanorods, Materials Science and Engineering A, 393: 80 – 82.

Jing Chen, Wei Lei, Weiqiang Chai, Zichen Zhang, Chi Li, Xiaobing Zhang, 2008. High field emission enhancement of ZnO-nanorods via hydrothermal synthesis, Solid-State Electronics, 52: 294 - 298.

Jinmin Wang, Lian Gao, 2004. Hydrothermal synthesis and photoluminescence properties of ZnO nanowires, Solid State Communications, 132: 269 - 271.

L.Z. Pei, H.S. Zhao, W. Tan, H.Y. Yu, Y.W. Chen, Qian-Feng Zhang, 2009. Hydrothermal oxidization preparation of ZnO nanorods on zinc substrate, Materials characterization, 60: 1063 - 1067.

Mingsong Wang, Yajun Zhou, Yiping Zhang, Eui Jung Kim, Sung Hong Hahn and Seung Gie Seong, 2012. Near-infrared photoluminescence from ZnO,Applied Physics letters, 100: 101906.

Xiangyang Ma, Hui Zhang, Yujie Ji, Jin Xu, Deren Yang, 2005. Sequential occurrence of ZnO nanopaticles, nanorods, and nanotips during hydrothermal process in a dilute aqueous solution, Materials Letters, 59: 3393 -3397.

Xiuping Jiang, Youzhi Liu, Yanyang Gao, Xuejun Zhang, Lihong Shi, 2010. Preparation of one-dimensional nanostructured ZnO, Particuology, 8: 383-385.

Y.Xi, C.G. Hu, X.Y. Han, Y.F. Xiong, P.X. Gao, G.B. Liu, 2007. Hydrothermal synthesis of ZnO nanobelts and gas sensitivity property, Solid State Communications, 141: 506 - 509.

Yong-hong Ni, Xian-wen Wei, Jian-ming Hong, Yin Ye, 2005. Hydrothermal preparation and optical properties of ZnO nanorods, Materials Science and Engineering B, 121: 42 - 47.

Zafar Hussain Ibupoto, Kimleang Khun, Martin Eriksson, Mohammad AlSalhi, Muhammad Atif, Anees Ansari and Magnus Willander, 2013. Hydrothermal Growth of Vertically Aligned ZnO Nanorods Using a Biocomposite Seed Layer of ZnO Nanoparticles, Materials, 6: 3584-3597.