Adsorption capacity of Methyl Orange using chitosan hydrogel beads extracted from Penaeus monodon shrimp shell waste
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Abstract
In this study, chitosan was extracted from Penaeus monodon shrimp shell waste and was used as a bio-sorbent to remove Methyl Orange (MO) dye in aqueous solution. Batch adsorption experiments were carried out to evaluate the influence of solution pH, chitosan dosage, contact time and initial MO concentration on the adsorption process. The study was conducted with varying contact time from 1 to 720 min, adsorbent dose from 0.1 to 3 g, adsorbate concentration from 10 to 200 mg/L, and pH from 3 to 10. The results showed that adsorption of MO by chitosan reached equilibrium after 240 min. The maximum adsorption capacity of MO calculated by Langmuir model was 23.1 mg/g obtained at room temperature (25°C), pH of 3, chitosan dose of 0.2 g and MO concentration of 50 mg/L. The kinetics of the adsorption process followed the pseudo-second-order kinetic model with the correlation coefficient R2 of 0.96. The Langmuir isotherm adsorption model described well the MO adsorption process, with R2 of 0.97. The study demonstrated that the chitosan can be extracted from shrimp shells simply and can be effectively used to remove Methyl Orange anionic dye in aqueous solution.
Tóm tắt
Trong nghiên cứu này, chitosan chiết xuất từ vỏ tôm sú Penaeus monodon được sử dụng làm chất hấp phụ sinh học để loại bỏ hợp chất màu methyl orange (MO) trong dung dịch. Nghiên cứu được tiến hành với thời gian tiếp xúc thay đổi từ 1 đến 720 phút, liều lượng chitosan từ 0,1 đến 3 g, nồng độ MO từ 10 đến 200 mg/L, và pH từ 3 đến 10. Kết quả cho thấy khả năng hấp phụ MO của chitosan đạt cân bằng sau 240 phút. Khả năng hấp phụ tối đa của MO tính toán bằng mô hình Langmuir là 23,10 mg/g thu được ở nhiệt độ phòng (25°C), pH = 3, khối lượng chitosan 0,2 g và nồng độ MO 50 mg/L. Động học của quá trình hấp phụ tuân theo mô hình động học biểu kiến bậc hai với R2 là 0,96. Mô hình hấp phụ đẳng nhiệt Langmuir mô tả tốt quá trình hấp phụ MO với R2 là 0,97. Kết quả chứng minh vỏ tôm sú có thể được chiết xuất thành chitosan có giá trị như một chất hấp phụ để loại bỏ thuốc nhuộm MO khỏi dung dịch.
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